OK...more of my .02. Remember that Octane allows for higher compression before self ignition. The more compression a motor has, the higher the temperature in the cylinder gets during the compression stroke (PV=NRT). With low octance gas, the temp could get to the ignition point before the spark starts the explosion which causes a knock. Just one thing though.....
The LS400 motor is a 4.0 liter V8 that only puts out 255HP. Considering that there are 2.2l 4 cylinders delivering this kind of power, it shows you exactly how low the compression/stress is on the motor. Thats why they last so long.
More importantly, the chance of detonation with low octane only occurs when the engine is under max load. This means you have your foot to the floor and are planning on getting somewhere fast.
The compression on the LS400 is very low and I rarely if ever have my foot on the floor. I use 89 around town and 87 on long hwy trips. Never had a knock. Anyone who tells you that they get better mileage, a cleaner engine or more power from high octance, doesn't understand what octane is and what it means. As an FYI, I use BP/Amoco gas in all of my cars.
Chet