There is a lot of really good information on Amsoil's website on all the different properties of oils and how they compare. Actually I work beside a plant that makes true synthetic oil and refining is my career. Motor oils are chain hydrocarbons, Refining fossil fuels to extract the correct length chain for motor lubrication is the traditional method of manufacture. The trouble is that distillation does not yield an absolutely pure specific chain length, In fact there is a small portion of very heavy oils up to and including tars and asphaltenes. This is one reason for the darker color of this type of motor oil. Synthetic oils are typically manufactured by using natural gas which is a mix of 2 and 1 carbon molecules. Using a catalytic process the molecules are reacted to combine into longer chains and making very pure, very specific chain lengths. They make anything from oil well drilling lubricants and soap additives with some of the longer ones to feedstock for synthetic motor oils for shorter ones. Where I work next door we use one product as a feed for making polyethylene plastic. I understand there is now a very different technology for making synthetic oil but I am not sure what that is yet. Anyway making a short story long, the lack of all the tars and heavy ends is why the lubrication is far better and engines run cooler on synthetic. It is also a reason why some people experience seal leakage when they make the switch on a vehicle with more miles on it. The synthetic is merely cleaning the dirt from the worn seals. As for switching back it is not a problem at all just a step down in quality.